Let $\sigma \in \mathbb R^{n\times n}$ be a positive semi-definite matrix ($n$ is an even number), and let the projections \begin{equation*} V_1 = \begin{pmatrix} I_{\frac{n}{2},\frac{n}{2}} & 0_{\frac{n}{2},\frac{n}{2}} \\ \end{pmatrix}, \end{equation*} \begin{equation*} V_2 = \begin{pmatrix} 0_{\frac{n}{2},\frac{n}{2}} &I_{\frac{n}{2},\frac{n}{2}} \end{pmatrix} \end{equation*}
where $I_{n,n}$ and $0_{n,n}$ are the identity matrix and the zero matrix of size $n\times n$, respectively.
Now what is the relation between the two quantities:
- $\operatorname{tr}(\sigma \log(\sigma))$, and
- $\operatorname{tr}(V_1 \sigma V_1^T \log(V_1 \sigma V_1^T)) + \operatorname{tr}(V_2 \sigma V_2^T \log(V_2 \sigma V_2^T)) $
Is there any generalization for the relation bound when the projection involves more than $V_1$ and $V_2$?
The $\log$ here is the matrix logarithm.
$\def\bb{\mathbb}$ Instead of the two partitions in your example, let's generalize to $m$ partitions.
Use the Kronecker product $(\otimes)$ to define matrix analogs of the standard base vectors $\,e_i\in{\bb R}^{m}$ $$\eqalign{ &E_1 &= e_1\otimes I_k,\quad &E_2 &= e_2\otimes I_k, \quad\ldots\quad &E_m &= e_m\otimes I_k \\ }$$ where $k=\left(\frac nm\right),\,$ assuming that $n$ is divisible by $m$.
Use the $\{E_i\}$ matrices to extract $k\times k$ blocks along the diagonal of $\sigma$ $$\sigma_1 = E_1^T\sigma E_1,\quad \sigma_2 = E_2^T\sigma E_2,\quad\ldots\quad \sigma_m = E_m^T\sigma E_m$$ This gives rise to the generalized functions $$\eqalign{ F_m = \sum_{i=1}^m\,{\rm Tr}\Big(\sigma_i\log(\sigma_i)\Big) \\ }$$ Using this notation, your first function is $F_{\tt1},\;$ your second is $F_{\tt2},\,$ etc.
and Rammus's answer has demonstrated that $$F_{\tt1}\ge F_{\tt2}\ge F_{\tt3}\ge \ldots$$
Another approach avoids the summation by using the all-ones matrix $J_k\in{\bb R}^{k\times k}$, the identity matrix $I_m\in{\bb R}^{m\times m}$ and the Kronecker/Hadamard $(\otimes/\odot)$ products to create a block-diagonal matrix $$\eqalign{ H_{m} &= I_m\otimes J_k \,\in\, {\bb R}^{n\times n} \\ B_{m} &= H_m\odot \sigma \\ }$$ Now the generalized functions can be written as $$F_m = {\rm Tr}\Big(B_m\;\log(B_m)\Big)$$ The advantage of this form is that it only requires a single evaluation of the log function, and the gradient is easy to calculate $$\frac{\partial F_m}{\partial \sigma} = I_n + H_m\odot\log(H_m\odot \sigma)$$