When we can say that two numbers are almost equal?

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I have two questions regarding 'approximation' (or a better word, if any, please see Q.2):

$1-$ I usually see terms like $\pi \approx 3.14159$ or $\pi \simeq 3.14159$ or $\pi \sim 3.14159$, etc. Which of the symbols $\approx$, $\simeq$, ... is the universally accepted or "standard notation" to use in Mathematics?

$2-$ What does actually approximation of a real number mean? $3$ and $5$ are the nearest numbers to $4$ but why there is no sign of e.g. $3 \approx 4$ in Mathematics? In other words, when defining approximation (i.e. "asymptotic equality of functions") in Analytic Number Theory we use the evaluation of of $\lim_{x \to \infty } (f(x)/g(x)) =1 \ \text{or} \ 0$ for "big or small O-notation" respectively. But what about numbers in lieu of functions?

PS, Sorry! Many subquestions in Q.2 are for better explanation of one question regarding understanding better the concept of the approximation.

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  1. The correct notation for an approximation (in the physicists' sense: this is not a mathematical concept) is $\;\color{red}\approx$. , as indicated by the name of the LaTeX command: \approx. $\color{red}\simeq$ is mostly used for ‘isomorphic to’, and $\color{red}\sim$ for ‘equivalence’.

  2. In mathematics, one only speaks a ‘approximation at a certain degree of precision’. This supposes the existence of a metric. If the metric is discrete, like in $\mathbf Z$, this is totally uninteresting. But you have the $p$-adic valuation, for instance, which is non-trivial.