Let $A_k$ be the set of all subsets of $P(\mathbb{N})$ with size $k$.
$A_k\in\mathbb{N}^k$ is countable for $k\in\mathbb{N}$.
Since $$P(\mathbb{N})=\bigcup_{k=1}^\infty A_k$$ which is a countable union of countable sets, $P(\mathbb{N})$ must also be countable.
However, $P(\mathbb{N})$ is known to be uncountable. Which step of the proof is wrong?
This shows that the set of all finite subsets of $\mathbb{N}$ is countable. This does not work for the full powerset. $\mathscr{P}(\mathbb{N})$ contains infinite subsets, for instance the subset of even integers is not contained in your union but is a subset of $\mathbb{N}$.