I have been trying to understand the following portion of this answer:
First, any field of order $p^n$ will have characteristic $p$, so the underlying additive structure of the group is necessarily $(\mathbb{Z}_p)^n$.
I hadn't heard of the term "characteristic" before. According to Wikipedia:
In mathematics, the characteristic of a ring $R$, often denoted $\text{char}(R)$, is defined to be the smallest number of times one must use the ring's multiplicative identity $(1)$ in a sum to get the additive identity $(0)$ if the sum does indeed eventually attain $0$. If this sum never reaches the additive identity the ring is said to have characteristic zero.
However, from this alone, I'm not being able to deduce how a field of order $p^{n}$ must have characteristic $p$. Also, how are we able to conclude that the underlying additive structure of the group is necessarily $(\Bbb Z_{p})^n$?
Short answer: the distributive law.
Long Answer: The additive group has order $p^n$, so it must have some nonzero element $s$ of additive order $p$. Then $1$ plus itself $p$ times multiplied by $s$ is zero, since it's the same thing as $s$ added to itself $p$ times. But this means $1$ plus itself $p$ times must be $0$ since $s\ne 0$. But then any field element $z$ added to itself $p$ times be zero, since that's the same as $z$ times $1$ added to itself $p$ times. So all nonzero elements of the additive group have order $p$.
But the structure for finite abelian group says that this must be $(\Bbb{Z}/(p))^n$, since a finite abelian group must be a direct product of cyclic groups, and the cyclic factors must all have order $p$ lest there be a nonzero element of some other order in their direct product.