A graph $G$ is distance transitive if for all vertices $u,v,w,x$ of $G$ such that $D_G(u,v) = D_G(w,x) $ implies that there exists a graph automorphism of $G$, $\psi \in \Gamma(G)$ such that $\psi(u) = w$, $\, \psi(v) = x$.
If we have a regular polytope, $\mathcal{P}$, (spherical, euclidean or hyperbolic) then if we take the graph whose vertices are the vertices of $\mathcal{P}$ and whose vertices are adjacent if and only if they share an edge in $\mathcal{P}$.
I should be clear that I do NOT know that this s true for all regular polytopes. But checking the few I can they seem to be so.
As stated by Chris Godsil in the comments, not all Platonic solids are distance-transitive: the 24-cell, 120-cell ans 600-cell are not distance-transitive.
Here is a complete list of polytopes that are distance-transitive (i.e. not only their edge-graph is distance-transitive, but also their Euclidean symmetry group acts distance-transitively on the skeleton):
See also Theorem 5.10 in my recent preprint:
However, the true reason for why exactly those polytopes are distance-transitive is more complicated. Chris Godsil should indeed be the perfect person to explain this, as it was essentially proven in his paper