Let's make the truth table:
$$\begin{array}{|c|c|c|} \hline p&(p) \text{ is true}&(p) \text{ is false}\\ \hline T&T&F\\ F&F&T\\\hline \end{array}$$
"$p$ is true" strictly agrees with $p$, while "$p$ is false" strictly disagrees with $p$. Why this asymmetry?
It just seems to oddly line up with natural language, and I am wondering if it does so just because we set it up that way on purpose. What I mean is that the proposition $p$ strictly agrees with the assertion $p$. In natural language, when someone says "If it is sunny, I will go to the beach" we expect that they are asserting that their statement is true, not that it is false; If we were assuming that they were asserting it is False, we would be wrong. In the same way, we seem to have "conveniently" set up logic so that when we see a written proposition $p$ we can assume the statement to be "$p$ is true" without changing anything.
Is there something fundamental about the definition of $T$ and $F$, or an axiom, that makes "True" special?
Let me rewrite my earlier answer completely since I think I understand a bit better what you are asking.
As I wrote above, you have to be careful when you start using mathematical logic in the real world. Often one hears statements like: I can mathematically prove that God exists or the opposite: I can mathematically prove that God does not exist. The problem here is that any mathematical proof involves only well defined terms. I might prove that all non-trivial proper subgroups of an Abelian group are normal. In this proof I would then use the definition of Abelian. I would use the definition of normal subgroup and a bunch of other things. All these terms have been defined elsewhere.
When I teach logic (low level) I also often give the examples like: Let $A$ be the statement that is is raining today. Then ... The problem here is that I haven't (mathematically) defined raining and I haven't defined today and so on. So this is actually a really bad example. We are trying to teach how mathematical logic is this precise way of doing mathematics, but then we star giving non-mathematical examples.
Now, I still do give these examples because one often can use ones intuition from the real world in logic. The basic task of negating a statement if many times done using your natural understanding of the words involved.
But this can be dangerous. My favorite example is the use of the word "or". In the real world, this (often) means exclusive or, but in mathematics $A$ or $B$ is true also if both $A$ and $B$ are true.
So what can you do?
Here is a suggestion that has helped me: Don't worry about the real world equivalences of mathematical terms and objects. Don't overthink things. Just do back to the definition. As such, saying that $p$ is false, is just the definition of negating $p$. And so, by definition $p$ is false has the opposite truth value of $p$.
Does that mean you can't/shouldn't ask about these things? No, not necessarily. But I would argue that the questions like "What is truth?" are more philosophical than mathematical.