Why is $\bar \phi : F(x) \rightarrow F(a)$ an isomorphism given $\phi : F[x] \rightarrow F(a)$ satisfy $\ker \phi = \{0\}$ ?
I've been trying to figure out why $\bar \phi$ is an isomorphism, and why $\phi$ is not an isomorphism.
I know that since $\ker \phi = \{0\}$ it follows that $\phi$ is one-to-one (please correct me if I'm wrong).
Now we only need to show $\overline{\phi}$ is surjective in order to show $\overline{\phi}$ is an isomorphism $F(x) \rightarrow F(a)$.
How can I see that $\bar \phi$ is an isomorphism $F(x) \rightarrow F(a)$? And why can I extend a one-to-one homomorphism on the polynomial ring to achieve this result?
OBS: $F(a)$ denote the smallest subfield of $E$ that contains $F$ and $\{a\}$.

The map you're looking at is evaluation at a point, $a$. There are two cases:
Case 1: $a$ is algebraic over $F$, in which case, there is a polynomial , $p(x)\in F[x]$ such that $p(a)=0$ showing that $\phi$ is not injective since it sends $F[x]\ni p(x)\to 0$.
Case 2: $a$ is transcendental. Then let ${p(x)\over q(x)}\in\ker \overline{\phi}$ be in reduced form for some polynomials $p,q\in F[x]$. This implies
Since $a$ is transcendental, $p(x)=0$, the zero polynomial, hence the kernel is trivial. On the other hand, this part of the proof has given us a vital clue:
Let $y={p(a)\over q(a)}\in F(a)$*, since $a$ transcendental, $q(a)\ne 0$ when $q\ne 0$ (here's where we use injectivity), but then $\overline{\phi}(p(x)/q(x))={\phi(p(x))\over\phi(q(x))}=y$ so that $\overline{\phi}$ is surjective.
*Note that since $F(a)$ is the smallest field containing $F$ and $a$, we can see that we can get all rational functions in $a$ with coefficients in $F$ in $F(a)$ because those are the things we can make using $F$, $a$, and the field operations, $\cdot, +, -, \div$, but also those are the only operations we're allowed, so all elements of $F(a)$ are rational functions in $a$ with coefficients in $F$, so that every $y$ has the claimed form.