I understand order of operations plays a large role, but I am still confused. I figured out:
If $-8^2 = -(8^2)$ then $-8^2 = -64$. Now the can do the inverse. To do the inverse we square root the entire expression. So $\sqrt{-64} = \pm8i$, or we can separate $-64$ into $-1 \cdot 64$ and we also get $\sqrt{-1}\cdot\sqrt{64} = i \cdot ±8 = \pm8i$. This means that we end up with different value to what we started with, meaning the inverse does not work. Now where $-8^2 = (8\cdot-1)^2$, we can say that $-8^2 = 64$, and doing the inverse we get $\sqrt{64} = \pm8$, which works.
So firstly, is there anything wrong with this proof. And secondly, if the proof above is valid, why is $-n^2$ seen as $-(n^2)$?
Because $-8^2 = -(8^2)$ is the way that needs the fewest parentheses in the long run.
Order-of-operations is a man-made concept. We could very well do math entirely without it, or with a different order, and no objective part of math would be any different. The only thing that would change is writability and readability. We humans have decided that that's what it should mean because it's the most convenient, so that's what it means.