Given a real number $r>0$. Is there a way to determine whether $r$ can be written as a (possibly infinite) sum of distinct terms of the form $1/n!$?
For example, if we want to determine whether $r$ can be written as a sum of distinct terms of the form $1/3^n$, we can write $r$ in base $3$, and check whether the representation contains only digits $0$ and $1$. This question asks for a similar checking method for sum of the form $\sum 1/n!$. One necessary condition is that $r<1+1/2!+1/3!+\ldots=e-1$. But that is probably not sufficient.
One necessary condition: if $r$ is such a sum, the fractional part of $n!r$ is $$n! r - \lfloor n!r \rfloor \le \sum_{k=n+1}^\infty \dfrac{n!}{k!} < \dfrac{1}{n} $$ So this says something about rational approximations of $r$. In particular, $\sin(\pi n!\; r) \to 0$ as $n \to \infty$.
Now for a randomly chosen $X \in [0,4]$, say, with uniform distribution, the random variables $\sin(\pi n! X)$ are identically distributed, and $\mathbb P(|\sin(\pi n! X)| < \epsilon) = O(\epsilon)$. This implies that the set of $r$ with such a representation has measure $0$.