We have $\binom{52}{5}$ ways of doing this. This will be our denominator.
We want to select all 4 aces, there are there are exactly $\binom{4}{4}$ ways of doing this.
Now we have selected 4 cards, and we need to select one more. That one card has to be the king of spades. Out of the 48 remaining cards, only one of them is our wanted one. This can be chosen in $\binom{48}{1}$ ways.
So is the answer:
$$\dfrac{\binom{4}{4}\binom{48}{1}}{\binom{52}{5}}=\dfrac{1}{54145}?$$
Is this correct?
If we look at it another way:
Then then our probability for the aces and specific king are $(4/52)\times (3/51) \times (2/50) \times (1/49) \times (1/48)$ which is a completely different here.
Which is the correct approach?
Assuming you just want those 5 cards in any order:
Since you have specified all 5 specific cards that you want, you don't need to consider the aces separately from the king. The probability of selecting these 5 cards is then
(Probability choosing any one of the 5) $\times$ (Probability of choosing one of the remaining 4) $\times$ ..., i.e. $$\frac{5}{52} \times \frac{4}{51} \times \frac{3}{50} \times \frac{2}{49} \times \frac{1}{48} = \frac{1}{54145} \times \frac{1}{48},$$ just to confirm what Ross Millikan said.
If, instead, you want the 4 aces before the king, we have $$\frac{4}{52} \times \frac{3}{51} \times \frac{2}{50} \times \frac{1}{49} \times \frac{1}{48}.$$