I don't understand the following lemma of the book Topology by J Munkres :
1- If a set $A$ with the mentioned properties exists there must be an example for it and so, it could help to understand both the lemma and the proof better? I tried some different types of uncountable subset of $\mathbb R$ but they don't work thus another question is
2- How to we know for sure (a proof) that there exists an $\Omega$ such that it is the smallest element of $C$ for which the section of $C$ by $\Omega$ is uncountable?
I would appreciate any simple clear detailed explanation.
PS. Definition. Let $X$ be a well-ordered set. Given $\alpha \in X$, let $S_{\alpha}$ denote the set $$S_{\alpha} = {\{x \ | \ x \in X \ \text{and} \ x < \alpha}\}.$$ It is called the section of $X$ by $\alpha$.

This lemma is demonstrating one of the more bizarre consequences of the fact that the axiom of choice lets us well-order any set. The consequence is that: There is a minimum uncountable ordinal.
Ordinal numbers are like cardinal numbers except they only apply to well-ordered sets, and give a finer distinction than cardinality for such sets. Two sets are of the same ordinal, if they are of the same cardinal and there exists an order isomorphism. That is, a one-to-one and onto function (thus showing their cardinal equivalence) that is also an order preserving map in both directions.
In this lemma, the ordinal of the set $A$ is the 2nd to least uncountable ordinal.