Will a prime $p^{0}$ be considered a unique prime in prime decomposition of a number? If the answer to the above question is yes then it breaks the uniqueness which the Fundamental Theorem of Arithmetic proposed.
If the answer is no, which I think is true, then why don't we count it.
Isn't it also the power of a prime?
That way I can say $4=2×2$ or $2×2×3^{0}$ and so on.
A typical statement of the Fundamental Theorem of Arithmetic is this one from Wikipedia:
0 is not a positive integer so powers $\alpha_i = 0$ are not allowed in the representation described here. You are correct that if 0 powers were allowed, the representation would no longer be unique.
It is true that $1 = 3^0$ is a power of prime. The error is in thinking that the FTA asserts that $n$ can be represented uniquely as a product of powers of primes. It claims only that it can be represented uniquely as a product of primes to positive powers.