The internal angle $\theta$ in a regular tetrahedron is $109.47^\circ$.
I can derive this using the following method and am now looking for alternative methods.
Take a regular tetrahedron with vertices $ABCD$ and centre $E$. The internal angle that I am referring to is of course any of the $\angle$ vertex-centre-vertex permutations such as $\angle AEB$.
The tetrahedron is composed of $4$ congruent triangular based pyramids, $ABCE$, $ABDE$, $ACDE$, and $BCDE$.
The height of each pyramid with $E$ as the apex is $h$ and the area of each base face is $A$.
The height of the regular tetrahedron is $(h+l)$ and the area of it's base face is also $A$.
The volume of the total tetrahedron is four times the volume of each pyramid.
Therefore: $$\frac{1}{3}A(h+l)=4 \frac{1}{3}Ah$$
This reduces to: $$l=3h$$
$$\cos \theta = -\frac{1}{3}$$
$$\theta = 109.47^\circ$$
I'm now looking for alternative methods for finding this internal angle.
Blue has already provided a convenient coordinate representation of a regular tetrahedron in a comment: $x,y,z=\pm1$ with $xyz=1$. All we have to do is choose two vertices, e.g. $\pmatrix{1\\1\\1}$ and $\pmatrix{-1\\-1\\1}$, and calculate the cosine using dot products:
$$ \cos\theta=\frac{\pmatrix{1\\1\\1}\cdot\pmatrix{-1\\-1\\1}}{\sqrt{\pmatrix{1\\1\\1}\cdot\pmatrix{1\\1\\1}}\sqrt{\pmatrix{-1\\-1\\1}\cdot\pmatrix{-1\\-1\\1}}}=-\frac{1}3\;. $$