Let $(\mathbb{N}\setminus\{1\}, \leq_p)$ with $x\leq_p y$ iff the largest prime factor of $x$ is $\leq$ the largest prime factor of $y$. Check if this defines a (total) order by checking the four order axioms.
To verify that this is a valid order I must verify the four axioms of order relations:
O1. Reflexivity: $x \leq x$.
O2. Anti-symmetry: $x \leq y \land y \leq x \Rightarrow x=y$.
O3. Transivitity: $x \leq y \land y \leq z \Rightarrow x \leq z$.
O4. Total order: $\forall x,y\in X: x\leq y \lor y \leq x$.
I really have no idea how to show this. I assume this wouldn't be enough for the first three axioms, right?
Let the largest prime factor of $x := p(x)$.
O1. $p(x) = p(x)$ and as such the axiom is fulfilled.
O2. If $p(x) \leq p(y) \land p(y) \leq p(x) \Rightarrow p(x)=p(y)$.
O3. ?
With O4 being shown through induction.
No, that's not quite the right approach. Here is what you need just for O1 and O2:
O1. We need to show $x \le_p x$ for any $x$ in the domain. Well, since $p(x) \le p(x)$ we have that $x \le_p x$, and as such the axiom is fulfilled.
O2. We need to show that if $x \le_p y$ and $y \le_p x$, then $x=y$ for any $x$ and $y$ in the domain. Well, if $x \le_p y$ and $y \le_p x$, then $p(x) \leq p(y)$ and $p(y) \leq p(x)$. This indeed means $p(x)=p(y)$ ... but does that mean $x=y$?
HINT