Let $F$ be a field and $K:F$ be a field extension such that $[K:F]=2$. Then
(i). If $Char(F)\neq 2$, then there exists $\alpha\in K^*$, $\alpha\notin F^*$, such that $K=F(\alpha)$ and $\alpha^2\in F^*$.
(ii). If $Char(F)=2$, then the above statement does not hold.
How to prove?
Let $x$ be any element in $K$ not in $F$. Since $\{1,x\}$ is a basis of $K$ as a $F$-vector space, we must have $$ x^2=ax+b $$ for some $a,b\in F$. Now consider $f\in F$ and compute $(x+f)^2=(a+2f)x+b+f^2$. So, if we choose $f=-\frac12a$, the element $\alpha=x+f$ is as wanted.
Yet, this can be done only if the characteristic is not $2$.