For what fields $K$ do there exist finite extensions $E/K$ (of degree $>1$) such that $K\cong E$?
If $K$ has finite degree over its prime field, then any finite extension $E/K$ has greater degree over the prime field, therefore $E\not\cong K$.
On the other hand, if $K=k(x)$ for some field $k$, then adjoining a formal square root $y$ of $x$ gives an extension $K(y)/K$ of degree $2$ such that $K\cong K(y)$, since $K=k(x)\cong k(y)=K(y)$.
I suspect the same holds for any field which contains an element which is transcendental over its prime subfield. However, I'm at a loss for how to deal with cases like infinite algebraic extensions.
Luroth's theorem on simple transcendental extension says what you have described is possible in every degree. Instead of going upwards you just have to search inward: For any transcendental $x$ over $K$ and any polynomial $f(x)$ with coefficients in $K$ the subfield of $K(x)$ generated by $f$ over $K$ is actually isomorphic to $K(x)$. Clearly $K(x)$ is an extension of degree = degree of $f$ over $K(f)$.