In general I want to know how to solve these types of questions. I know that you have to use the binomial theorem.
or $\binom{99}{1}-\binom{99}{2}+\binom{99}{3}-\binom{99}{4}+...+-\binom{99}{96}+\binom{99}{97}-\binom{99}{98}$
Please don't just give me the answers I want to understand what you are doing.

Notice that from a class of $n$ people, the number of ways to choose $i$ people to be in a team is equal to the number of ways to choose $n-i$ people to be not in the team. That is, we have:
$$\binom{n}{i} = \binom{n}{n-i}$$
Hence by pairing the $i$-th and $(n-i)$-th term, they get cancelled out.
$$\sum_{i=0}^{11} \binom{13}{i}=\binom{13}{0}-\binom{13}{1}$$
Similarly for the second question.
Pair $\binom{99}{1}$ with $\binom{99}{98}$. Pair $\binom{99}{2}$ with $\binom{99}{97}$ and etc.