Given the real numbers $a_1,a_2,b_1,b_2,c_1,c_2\in [0,1]$. Suppose we know that the set $$\begin{cases}x+y+z=1 \\a_1\le x \le a_2\\ b_1\le y \le b_2\\ c_1\le z \le c_2\\ \end{cases}$$ is a surface (not empty and not reduced to a point).
Is there a criterion that enables us to know if the surface is a triangle?
For example, if $a_1=b_1=c_1=0$ and $a_2=b_2=c_2=1$, then the surface is a triangle (the standard 2-simplex).
But, for example, the plot of $$\begin{cases}x+y+z=1 \\0\le x \le 0.2\\ 0.1\le y \le 0.6\\ 0.6\le z \le 0.7\\ \end{cases}$$ is not a triangle.

Let me use $S$ to denote the rectangular solid defined by your three inequalities.
Also let $F(x,y,z) = x+y+z$. We are interested in plane defined by the equation $F(x,y,z)=1$ which I'll denote $F_1$
So your question comes down to whether $S \cap F_1$ is a plane. To determine the answer, evaluate the function $$F(x,y,z)=x+y+z $$ on each of the eight points forming the vertices of $S$, namely $$P_{i,j,k} = (a_i,b_j,c_k), \quad i,j,k \in \{1,2\} $$ Now count: let $N_+$ be the count of how many of those eight values are $\ge 1$; and let $N_-$ be the count of how many are $\le 1$.
The intersection $S \cap F_1$ will be a triangle if and only if $N_- = 7$ or $N_+ = 7$.
Here's an intuitive explanation of why this is true; I'll leave out detailed proofs, which should involve nothing more than simple case analysis involving inequalities.
Imagine $S$ starts above the plane $F(x,y,z)=1$ and then moves downwards, passing through the plane. At the first moment that $S$ touches the plane, it touches it at the point $(a_1,b_1,c_1)$, and at that moment we have $N_-=1$ and $N_+ = 8$ and the intersection is just that point. Then, as $S$ moves a little further, $N_-=1$ and $N_+=7$ and the intersection is a triangle.
As $S$ continues to pass further through the plane, the intersection continues to be a triangle up until the first moment that one of the three points $(a_2,b_1,c_1)$ or $(a_1,b_2,c_1)$ or $(a_1,b_1,c_2)$ touches the plane. If $S$ passes just a bit further, one obtains a polygon with 4 to 6 sides, and both of $N_-,N_+$ are $\le 6$. This continues up until the last moment that one of the three points $(a_1,b_2,c_2)$ or $(a_2,b_1,c_2)$ or $(a_2,b_2,c_1)$ touches the plane. At that moment the intersection becomes a triangle again, and continues until the moment that $(a_2,b_2,c_2)$ touches the plane, at which moment we have $N_- = 8$ and $N_+ = 1$.