In terms of the connection coefficients
$$R_{abc}^d = \partial_a \Gamma_{bc}^d-\partial_b \Gamma_{ac}^d - \Gamma_{be}^d\Gamma_{ac}^e+\Gamma_{ae}^d\Gamma_{bc}^e$$
Pick an event $A$ and choose coordinates such that $\partial_a g_{bc} = 0$ at $A$... So at the event $A$, but not elsehwere in general,
$$R_{abcd} = g_{de}\partial_a(\Gamma_{bc}^e) - g_{de}\partial_b(\Gamma_{ac}^e)$$
Where has this last equation (RHS) come from?
Because of the hypothesis at event A (which is called Riemann normal coordinates at the point in question), all the Christoffel symbols $\Gamma^a_{bc}$ (but not their derivatives) vanish at A. The presence of the $g_{de}$ is to lower the index and get $R_{abcd}$ from $R^d_{abc}$.