Difference between $k[x,1/x]$ and $k(x)$

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What is the difference between $k[x,1/x]$ and $k(x)$ ?

Any rational polynomial with coefficients from $k$ belongs also to $k[x,1/x]$ or not?

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No. You can't write $\frac1{x+1}$ as $\frac{a_{-n}}{x^n}+\frac{a_{-n+1}}{x^{n-1}}+\cdots+a_nx^n$.