
In $△ABC$, point $E$ on $AC$ such that $AE = 2 EC$ and $\angle ABE = 2 \angle EBC$, point $F$ on $BE$ such that $AF \perp BE$, and point $D$ on $AC$ such that $AD=DC$.
Prove that $DF \perp BC$.
I (Michael) tried to prove that $\overrightarrow{DF}\cdot\overrightarrow{BC}=0$, but it gives very ugly computations.

(I've renamed a couple of points. $P$ is the foot of the perpendicular from $A$ to $\overline{BE}$, and $M$ is the midpoint of $\overline{AC}$. I've also conveniently subdivided $\overline{AC}$ into sixths, to clearly indicate both trisection by $E$, bisection by $M$, and the key ratio in $(3)$.)
Drop a perpendicular from $C$ to $Q$ on $\overleftrightarrow{BE}$. Then, $$\triangle APE \sim \triangle CQE \quad\text{with}\quad |\overline{AE}|:|\overline{CE}| = 2:1 \tag{1}$$ so that $$\frac{2}{1} \;=\; \frac{|\overline{AP}|}{|\overline{CQ}|} \;=\; \frac{|\overline{AB}| \sin 2\delta}{|\overline{BC}|\sin\delta} \;=\; \frac{|\overline{AB}|\cdot 2 \sin\delta\cos\delta}{|\overline{BC}|\cdot\sin\delta} \quad\to\quad |\overline{BC}| = |\overline{AB}|\cos\delta \tag{2}$$
As @Alfred did, we'll extend $\overline{BE}$ to a point (we'll call ours $A^\prime$) such that $\overline{AB}\cong\overline{A^\prime B}$. By $(1)$, we know that $\triangle A^\prime B C$ has a right angle at $C$; moreover, this triangle is congruent to both $\triangle ABC^\prime$ and $\triangle A^\prime B C^\prime$, where $C^\prime$ is the midpoint of $\overline{AA^\prime}$.
Note that $\overline{C^\prime C} \parallel \overline{AP}$ (as both are perpendicular to $\overline{PA^\prime}$), and $\overline{C^\prime C}$ meets the midpoint of $\overline{PA^\prime}$ (by, say, the Midsegment Theorem applied to $\triangle APA^\prime$). We may conclude that $\square PCA^\prime C^\prime$ is a rhombus, which implies $\overline{AC^\prime} \cong \overline{CP}$. Consequently, $\square APCC^\prime$ is a parallelogram, with mutually-bisecting diagonals: $M$, the midpoint of $\overline{AC}$, coincides with the midpoint of $\overline{PC^\prime}$. Thus, $P$, $C^\prime$, $M$ are collinear, with a shared line that, being parallel to $\overline{A^\prime C}$, must be perpendicular to $\overline{BC}$. $\square$