Can someone give me a simple, concrete example of a homotopy, which is not a path homotopy?
Let $f, f'$ be continuous maps from $X$ to $Y$, and let $F: X \times I\to Y$ a continuous map such that $F(x,0) = f(x)$ and $F(x, 1) = f'(x)$. Then $f$ is homotopic to $f'$.
I understand path homotopies (the path can be deformed but the endpoints stayed fixed), but now I don't see what a homotopy is. I think the notation is what is messing me up, so can you explain what are the spaces $X$, $Y$ in your example? And what are your maps $f$, $f'$?
To match your notation, let $X=\mathbb{R}$ and let $Y=\mathbb{R}$ as well. Then we can define two maps $f:\mathbb{R} \to \mathbb{R}$ by $f(x)=0$ and $f':\mathbb{R} \to \mathbb{R}$ by $f'(x)=x$. The homotopy between the maps is given by $F: \mathbb{R} \times I \to \mathbb{R}$ by $F(x,t)=tx$.
We can see that $F(x,0)=0\cdot x = 0 = f(x)$ and $F(x,1) = 1 \cdot x = x = f'(x)$.
This homotopy "shrinks" the identity map down to the zero map.
A homotopy is more general than a path homotopy. A homotopy continuously deforms one function to another function, whereas a path homotopy continuously deforms path functions.