I'm trying to learn about topological groups but I can't seem to google anything that provides a simple and clear example of how the set of elements of a group correspond to open sets of a topology.
Also, what does it mean for a group binary operation to be continuous. I would think that is always true since if $g_1\in G$ is open then then the inverse operation from $g_2\in G$ to $g_1$ would always map to an open discrete set.
It might be easier to think of a topological group as a topological space with a group structure rather than a group with a topology.
Let $X$ be a topological space. This means that certain subsets of $X$ are in a family $\tau\subset\mathcal{P}(X)$ such that the usual axioms apply.
Now assuming the axiom of choice, there is a group structure on $X$. That is maps $m:X\times X\rightarrow X$ and $\operatorname{inv}:X\rightarrow X$ --- and an element $e\in X$ --- such that $(X,m)$ is a group.
When $m$ and $\operatorname{inv}$ are continuous then we say that $(X,m)$ is a topological group.
This means that if $U\in\tau$, $m^{-1}(U)$ is an open set in the product topology of $X\times X$; and $\operatorname{inv}^{-1}(U)\in\tau$ also.