$\newcommand\Q{\mathbb Q}$
I am having a difficult time trying to figure this out. I suspect it is true, but cannot really convince myself to it. Here is the setting and the question:
I have a Galois field extension of $\Q$, let's call it $K$. Also I know that the maximum real subfield of $K$, let's call it $L:=K\cap\mathbb R$, is not Galois over $\Q$ but with Galois closure $K$. Let $f$ be the minimal polynomial of a primitive element of $K$ over $\Q$ and denote $Z(f)$ the set of zeros of $f$ in $K$ (so all roots of $f$ are non-real and we can write $K=\Q(\alpha)$ for some $\alpha\in Z(f)$). I want to convince myself that there is a field automorphism $\sigma\in\mathrm{Gal}(K/\Q)$ and an element $z\in Z(f)$ such that its complex conjugate pairs are not mapped by sigma to another complex conjugate pair i.e. $$\{\sigma(z),\sigma(\bar z)\}\neq \{\sigma(z),\overline{\sigma(z)}\} $$
I feel this is true but cannot really show this.
Well, what does it mean that $L$ is not Galois over $\mathbb{Q}$? It means that $Gal(K/L)$ is not a normal subgroup of $Gal(K/\mathbb{Q})$. But $Gal(K/L)$ just contains the identity and complex conjugation, and so this is a normal subgroup iff complex conjugation commutes with every element of $Gal(K/\mathbb{Q})$. So, there exists some $\sigma\in Gal(K/\mathbb{Q})$ that does not commute with complex conjugation. This means that $\sigma(\overline{\alpha})\neq\overline{\sigma(\alpha)}$, since $\alpha$ generates $K$ over $\mathbb{Q}$.