In the first representation theorem, the notion of the core of a sesquilinear form appears. What is the intuition behind this notion, in context of this theorem and in general? I appreciate any comments and answers!
(Here are some relevant definitions and background. All excerpts are from Kato's Perturbation Theory for Linear Operators, pp.308-322.)

The definition of core is given in the same Kato's book that you cited at page 317 for a closed sectorial form and at page 166 for a closed operator.
I refer to this last (but the first is a particular case).
Note that the closure of $\mathbf{G}$ is in the induced topology on $X\times Y$.
As an intuition i think that we can see a core $\mathbf{D}$ as a subspace of the domain of $T$ such that if we take a restriction of the operator $T$ to this subspace we can reconstruct its graph by the values on $\mathbf{D}$ taking limits of convergent sequences $(u_n,Tu_n)$ for $u_n \in \mathbf{D}$.