Could someone explain to me how to do what the title states?
For an arbitrary vertex in an arbitrary polygon how to determine which of the vertex's 2 angles lies inside the polygon knowing only the vertices' coordinates?
- the dimension is 2d, i.e. the polygon lies on the XY plane. There is no problem to add a dimension, if necessary
- I know all the coordinates of the vertices.
My problem is that the polygon may be very arbitrary, e.g. like the below one, and how do I know which of the 2 angles lies inside the polygon (the blue one or the green one)?

If you have a list of the vertices taken clockwise (for instance): $$ (V_1, V_2, \dots, V_n) $$ then you must take $\alpha_k=\angle V_{k-1}V_kV_{k+1}$ so that side $V_{k-1}V_k$ is carried to side $V_kV_{k+1}$ by a counter-clockwise rotation of $\alpha_k$.
In practice, that means that if $(V_{k-1}-V_k)\times(V_{k+1}-V_k)>0$ then you must take $\alpha_k<180°$, if $(V_{k-1}-V_k)\times(V_{k+1}-V_k)<0$ then you must take $\alpha_k>180°$, where:
$$ u\times v=\det\pmatrix{u_x & u_y \\ v_x & v_y}. $$