I have changed this problem by adding some conditions. giving that $\forall{i=1...n}, Pr(a_i > 0) < e^{-d}$ where $Pr$ is the probability and $d$ is an positive integer, $a_i$ are iid, please give a bound for $Pr(\sum_{i=1}^{i=n}{a_i} > 0) < $ ???.
we can simply use $$Pr(\sum_{i=1}^{i=n}{a_i} > 0) = 1-Pr(\sum_{i=1}^{i=n}{a_i} \le 0) \le 1-Pr(a_1 \le 0, a_2 \le 0, ..., a_n \le 0)=1-(1-e^{-d})^n$$, but is there a better bound? a better bound means it should be less than $1-(1-e^{-d})^n$
Let $n=2$, $d=1$ and $a_i = 1_{H_i}$ where $\{H_n\}_{n \ge 1}$ is independent coin tossing with $Pr(H_n) = p < e^{-1}$
$$Pr(\sum_{i=1}^{i=2}{a_i} > 0) = 1-(1-p)^2 \ge e^{-1}$$
for $p \in [1-\sqrt{\frac{e-1}{e}},\frac1e) $
Generally,
$$Pr(\sum_{i=1}^{i=n}{a_i} > 0) = 1-(1-p)^n \ge e^{-d}$$
for $p \in [1-(\frac{e^d-1}{e^d})^{\frac1n},\frac1{e^d}] $
But $1-(1-p)^n < 1-(1-e^{-d})^n$
That covers the cases where $a_i$'s are those indicators. You can try out different indicators, but I guess we should assume independence of the $a_i$'s. Then you can try $a_i$'s to be simple functions. The inequality holds true for $a_i=-1_{H_i}$, any $n$ and any $d$ obviously. Then you can try nonnegative then integrable.
You may be interested in Chebyshev's inequality.