I'm trying to find functions to describe relationships that are simply described in english or graphically.
For example, for $x \leq 0$, $f(x) = 1$; and as $x$ gets bigger $f(x)$ approaches $0$ ($y=0$ is an asymptote). The graph looks something like this: sketch of graph.
How do I work backwards to turn this into a mathematical function of the form: $$f(x) = something$$
You can write down all functions which may apply to your problem and then sort them out.
For $x\leq0$ you can simply take $f(x)=1$.
For $x>0$ you can take functions in $\mathcal O\big(\frac1x\big)$ because $\frac1x\to 0$ for $x\to\infty$. In order to make the whole function continuous let‘s take $\frac1{x+1}$.
Putting all together we get $$ f(x)= \begin{cases} 1, &\text{for } x<0\\ \frac1{x+1},&\text{for } x\geq0 \end{cases}. $$