The following problem is proposed by Cornel Valean:$$\operatorname{P.V.} \int_0^1 \frac{1}{x (1-x)}\arctan \left(\frac{8 x^2-4 x^3+14 x-8}{2 x^4-3 x^3-11 x^2+16 x+16}\right) \textrm{d}x=\log \left(\frac{5}{4}\right) \arctan\left(\frac{1}{2}\right).$$
The question is how can we prove this equality without using the main result in this paper and without the use of complex numbers?

Too long for a comment.
Since $$T(x)=\dfrac{-4x^3 +8x^2+14x-8}{2x^4-3x^3-11x^2+16x+16} =\dfrac{R(x)-S(x)}{1+R(x)S(x)},$$ where $$R(x)=\dfrac2{x^2-x-4},\quad S(x)=\dfrac{4x}{2x^2-x-4},\quad x\in[0,1],\tag1$$ (pointed by Sophie), then $$\arctan T(x) = \arctan R(x) - \arctan S(x),$$ (see also WA plot)
$$I=\int\limits_0^1\arctan T(x)\; \dfrac{\text dx}{x(1-x)} =\int\limits_0^1\arctan T(x)\;\left(\dfrac1x+\dfrac1{1-x}\right)\,\text dx, $$$$ I=\int\limits_0^1\big(2\arctan R(x)-\arctan S(x)-\arctan S(1-x)\big)\; \dfrac{\text dx}{x},\tag2$$ wherein $$S(1-x)=\dfrac{4-4x}{2x^2-3x-3}.\tag{1a}$$ This transformation makes the integral convergent, and the numerical integration gives $$I\approx 0.10345,99740\,30782\,04062\,03377\,83301\,52783\,80081\,8.$$ Obtained result exactly corresponds to the OP value.
However, analytical result does not obtained.
We can additionally decompose arctangents of $\;R(x),S(x),S(1-x)\;$ to the elementary terms.
Assuming $$R(x) = \dfrac{(a+2cx)+(b-2cx)}{1-(a+2cx)(b-2cx)},$$ and taking in account coefficients proportionality, one can get $$ \begin{cases} a+b=8c^2\\ 2c(b-a)=4c^2\\ ab-1=16c^2\\ c>0 \end{cases}\Rightarrow \begin{cases} a=4c^2-c\\ b=4c^2+c\\ 16c^4-17c^2-1=0\\ c>0 \end{cases} $$$$ c=\sqrt{\dfrac{\sqrt{353}+17}{32}}\approx1.05753\,68526,\tag3 $$$$ a=4c^2-c,\quad b=4c^2+c,$$ $$\arctan R(x)=\arctan(a+2cx)+\arctan(b-2cx),$$ $$\arctan R(x)=\arctan(4c^2+c(2x-1))+\arctan(4c^2-c(2x-1)).\tag4$$
Similarly, assuming $$S(x) = \dfrac{-4x}{-2x^2+x+4} = \dfrac{(gx+d)+(hx-d)}{1-(gx+d)(hx-d)},$$ one can get $$ \begin{cases} g+h=-(1+d^2)\\ 4d(g-h)=1+d^2\\ 2gh=1+d^2\\ d>0 \end{cases}\Rightarrow \begin{cases} (2g+1)+(2h+1)=-2d^2\\ (2g+1)(2h+1)=1\\ 2d((2g+1)-(2h+1))=1+d^2\\ d>0, \end{cases} $$$$ \begin{cases} (2g+1),(2h+1)=-d^2\pm\sqrt{d^4-1}\\ 4d\sqrt{d^4-1}=1+d^2\\ d>0, \end{cases} \begin{cases} 16d^4-17d^2-1=0\\ g,h=\dfrac{-(1+d^2)\pm\sqrt{d^4-1}}2\\ d>0, \end{cases} $$$$ g,h=\dfrac{1+d^2}{-(1+d^2)\mp\sqrt{d^4-1}} =\dfrac{4d}{-4d\mp1}, $$$$ d=\sqrt{\dfrac{\sqrt{353}+17}{32}}=c,\quad g = -\dfrac{4c}{4c+1},\quad h = -\dfrac{4c}{4c-1}, $$$$ \arctan S(x) = \arctan(gx+d)+\arctan(hx-d) $$$$ \arctan S(x) = \arctan\dfrac{4c^2+c-4cx}{4c+1}-\arctan\dfrac{4c^2-c+4cx}{4c-1} \tag5 $$$$ \arctan S(1-x) = \arctan\dfrac{4c^2-3c+4cx}{4c+1}-\arctan\dfrac{4c^2+3c-4cx}{4c-1} .\tag6 $$ Obtained integrals allow analytical calculation via integral logarithmic function of complex argument.
Taking the real parts, one can get $$J(p,q,x) = \int \arctan(px+q)\,\dfrac{\text dx}{x}=J_1(p,q,x)+J_2(p,q,x)+J_3(p,q,x),\tag7$$ where $$J_1(p,q,x) = (\ln p+\ln x)\arctan(px+q),$$ $$J_2(p,q,x)=\dfrac12\Im\left(\text{Li}_2\left(1+\dfrac{px}{q-i}\right)-\text{Li}_2\left(1+\dfrac{px}{q+i}\right)\right), $$$$ J_3(p,q,x)=\dfrac12\Im\big(\ln(q+i)\ln(1-i(px+q))-\ln(q-i)\ln(1+i(px+q))\big).$$ From $(4),(5),(6)$ should that the term with $\;\ln x\;$ does not influent to the goal definite integral. Therefore, we can assume $$J_1(p,q,1)-J_1(p,q,0) = \ln p\arctan\,\dfrac p{1+(p+q)q}.\tag8$$ Also, $$J_2(p,q,1)-J_2(p,q,0) = \dfrac12\Im\left(\text{Li}_2\left(1+\dfrac{p}{q-i}\right)-\text{Li}_2\left(1+\dfrac{p}{q+i}\right)\right),$$ $$J_3(p,q,x) = \dfrac12\Im\bigg(\ln(q+i)\ln(1-i(px+q))+\ln(q+i)\ln(1+i(px+q)) $$$$ -\ln(q+i)\ln(1+i(px+q))-\ln(q-i)\ln(1+i(px+q))\bigg)$$ $$= \dfrac12\Im\bigg(\ln(q+i)\ln(1+(px+q)^2)-\ln(q^2+1)\ln(1+i(px+q))\bigg),$$ $$J_3(p,q,1)-J(p,q,0) = \dfrac12\Im\bigg(\ln(q+i)\ln\,\dfrac{1+(p+q)^2}{1+q^2}-\ln(q^2+1)\ln\dfrac{1+i(p+q)}{1+iq}\bigg) $$$$ = \dfrac12\Im\bigg(\ln(q+i)\ln\,(1+(p+q)^2)-\ln(q^2+1)\ln\dfrac{(1+i(p+q))(q+i)}{1+iq}\bigg) $$$$ = \dfrac12\Im\bigg(\ln(q+i)\ln\,(1+(p+q)^2)-\ln(q^2+1)\ln\dfrac{(1+i(p+q))(q+i)(1-iq)}{1+q^2}\bigg) $$$$ = \dfrac12\Im\bigg(\ln(q+i)\ln\,(1+(p+q)^2)-\ln(q^2+1)\ln((q+i)^2(p+q-i)) \bigg) $$
But this approach contradicts to the OP requirements.