$$\pi\cdot\frac{(-1)^{n+1}}{2^{2n-3}}\sum_{k=0}^{n-1}(-1)^k{2n\choose k}(n-k)=\frac{(2n-3)!!}{(2n-2)!!}\frac{\pi}{2},\ \ \ \ n\in\Bbb{N}^+\tag1$$
I have a feeling that $(1)$ might be true. Contour integration yielded the LHS while the RHS is given in the answer key. To prove this result without induction, I first I distributed the sum, and showed that
$$\begin{align} n\sum_{k=0}^{n-1}(-1)^k{2n\choose k}&=n\sum_{k=0}^{n-1}(-1)^k{2n\choose k}{n-k-1\choose n-k-1}\\&=n\sum_{k=0}^{n-1}(-1)^{k+n-k-1}{2n\choose k}{-1\choose n-k-1}\\ &=n(-1)^{n-1}{2n-1\choose n-1}.\end{align}$$
I am not sure what to do with
$$\sum_{k=1}^{n-1}k(-1)^k{2n\choose k}\tag2$$
since this has the additional $k$. I thought about using some definite integral substitutions for $k$ but those did not get me anywhere. A hint to solving $(2)$ ought to suffice though complete answers are also welcome.
EDIT. The original equality in $(1)$ does not hold. I had messed up the denominator. The correct identity is
$$\pi\cdot\frac{(-1)^{n+1}}{2^{2n-1}}\sum_{k=0}^{n-1}(-1)^k{2n\choose k}(n-k)=\frac{(2n-3)!!}{(2n-2)!!}\frac{\pi}{2},\ \ \ \ n\in\Bbb{N}^+\tag{1'}.$$
Thanks to Felix Marin for pointing this out!
We have $$ k\binom{2n}{k} = \frac{(2n)!}{(k-1)!(2n-k)!} = 2n\binom{2n-1}{k-1} $$
hence it follows that:
$$ A(n) = \sum_{k=1}^{n-1} k(-1)^k \binom{2n}{k} = 2n\sum_{k=1}^{n-1}(-1)^k \binom{2n-1}{k-1} = -2n\sum_{k=0}^{n-2}(-1)^k \binom{2n-1}{k} $$ and you already know how to deal with the last sum by exploiting symmetry.
An alternative comes from experience: the RHS of your identity is clearly related with integrals of the form $\int_{0}^{\pi/2}\sin(x)^{2n}\,dx$. So we may start considering that
$$(e^{it}-e^{-it})^{2n} = \sum_{k=0}^{2n}\binom{2n}{k}e^{(2n-k)it}e^{-kit}(-1)^k $$ differentiate both sides with respect to $t$ $$ \frac{d}{dt}\left(2i\sin t\right)^{2n} = 2i\sum_{k=0}^{2n}\binom{2n}{k}(-1)^k(n-k)e^{(2n-2k)it} $$ then isolate the contributes given by $k\in\{0,\ldots,n-1\}$ by multiplying both sides by $(e^{-2nit}+e^{-(2n-2)it}+\ldots+e^{-2it})$ (that is a simple geometric sum) and integrating over $(0,2\pi)$.