While solving a totally different problem , I made observation that in a triangle , if side $s_1$ has length greater than $s_2$ , then angle opposite to $s_1$ say to $θ_1$ is larger than angle opposite to $s_2$ say $θ_2$.
I verified by drawing several triangles . Can someone tell if it's right and prove it ?

It is a well-known property. It is in fact Euclid's Proposition 18 in his first book of the Elements. See this link for Euclid's argument.