In equation involving absolute value one solution might get rejected, why is that?

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For example the equation $|2x-1|+3=4x$,

We can get two equations out of that, $2x-1=4x-3$ and $2x-1=-(4x-3)$. Solve the first one we get $x=1$ and for the second one $x=2/3$. But when you substitute 2/3 into the original equation, you get 10/3=8/3, which is clearly wrong. My answer sheet says the answer is rejected, but if we follow all steps correctly and get to a solution, how can it still be wrong? It's like solving $5=3+x$ and x somehow doesn't equal to two.

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Because: $$|2x-1|+3=4x \implies 2x-1=4x-3 \lor 2x-1=-(4x-3)$$ and the converse is false.

Which means that any solution of LHS is also solution of RHS, but the converse is not necessary true. This is why if you perform a non-reversible derivation, you need to check the solutions in the original equation.

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The absolute value of a number cannot be negative.

Observe that $2x - 1 \geq 0 \implies x \geq \dfrac{1}{2}$.

Hence, $|2x - 1| = 2x - 1$ if $x \geq 1/2$. On the other hand, if $x < 1/2$, then $2x - 1 < 0$, so $|2x - 1| = -(2x - 1) = -2x + 1 > 0$. Therefore, we obtain the piecewise definition

$$ |2x - 1| = \begin{cases} 2x - 1 & \text{if $x \geq \dfrac{1}{2}$}\\[2 mm] -2x + 1 & \text{if $x < \dfrac{1}{2}$} \end{cases} $$

Thus, we must consider cases, depending on whether $x \geq 1/2$.

Case 1: If $x \geq 1/2$, \begin{align*} |2x - 1| + 3 & = 4x\\ |2x - 1| & = 4x - 3\\ 2x - 1 & = 4x - 3\\ 2 & = 2x\\ 1 & = x \end{align*} Since $1 \geq 1/2$, $x = 1$ is a solution, as you can verify by direct substitution.

Case 2: If $x < 1/2$, \begin{align*} |2x - 1| + 3 & = 4x\\ |2x - 1| & = 4x - 3\\ -2x + 1 & = 4x - 3\\ 4 & = 6x\\ \frac{2}{3} & = x \end{align*} However, $2/3 \geq 1/2$, so it is not satisfy the restriction that $x < 1/2$. Therefore, $x = 2/3$ is not a valid solution, as you can verify by direct substitution.