Of course radians generally come in ratios of π.
So is 1 rad important/useful/special? Or, for that matter, is any integer radian measure important?
Besides being approximately 57°, I can't seem to find anything.
As an alternative way of asking this question — are the values of $sin(1)$, $cos(1)$, $tan(1)$, etc important (I know they are transcendental)?
Radians do not come in ratios of π, we just call a half rotation π radians, it is the natural thing to do. Degrees are, in my opinion, nonsense. What is the significance of the number 180? It is very clear that π has a very real connection to angles - πr is the length of the arc of a semicircle radius r. It is natural to associate π with this type of angle, then.
Are integer radians very "important?" I don't know what that means, nor do I know why they should be important.
Radians are a very natural angle measure. Many formulas become simplified, and even simple things that we take for granted (d/dx sin(x) = cos(x)) are only true for an argument in radians. It is because the relationship between angles and the number π is very concrete.