It seems reflexive, antisymmetric and transitive. My mathematics training is limited though and I would love proof or contradiction. A quick search turns up many references cataloging on stochastic orderings - e.g. stochastic dominance, hazard rate order, etc. None so far seems to mention this most basic one though.
Is the relation defined as $(A,B) \in \leq_q$ if $p(A \leq B) \geq q$ a partial order too? I feel like it should be - at least for $q>1/2$, and maybe assuming something about the dependence between any pair $A,B$? - but need help to prove it.
No, as it is not anti-symmetric.
Anti-symmetry requires that $a≤b\,\,\&\,\,b≤a\implies a=b$.
To get a counter example in your case, suppose that $A\in \{0,1\}$ with probabilities $\{.99,\, .01\}$ and $B\in \{0,2\}$ also with probabilities $\{.99,\, .01\}$ Then, following your definition we see that $A≤B$ and $B≤A$ yet they are not the same variable.
More broadly, you get $A≤B$ and $B≤A$ any time $A=B$ with probability $>\frac 12$, yet that relation does not imply equality of the variables, even if you interpret "equality" to mean "identical distribution".