In Cartesian coordinates, a point or vector is defined with an x distance or magnitude, a y distance or magnitude, and in 3 dimensions, a z distance or magnitude.
In 2 dimensional polar coordinates, a point or vector is defined by a radius and an angle.
In 3 dimensions, we have cylindrical coordinates and spherical coordinates.
In cylindrical coordinates, we have a vertical distance for a point or vector, and an angle and radius for the "circle" in the cylinder.
In spherical coordinates, we have two angles and one radius.
But is it possible for a coordinate system to be defined with three angles and no radius?

The question is a bit vague, coordinate system in particular would need a proper definition to give a rigorous answer.
But essentially the answer is yes. Imagine your space is a circle. Then a coordinate system is just an angle. You can generalise this to $n$ dimensions in at least two ways. You can take the product of $n$ circles, an $n$-torus, where natural coordinates are $n$ angles, or you can take the $n$-sphere, where again you can use $n$ angles as coordinates (that may be hard to visualise, but a 2-sphere is easy, and the angle are latitude and longitude).
Or you could decide you are work with conformal quantities - essentially you are defining an equivalence relation so that only angle matters and points along the same direction are identified (this is pretty loosely stated, look up conformal geometry or conformal transformation of a metric tensor if you are interested).