I just watched a video lecture which proved that the fundamental group of the $1-$sphere $S^1$ is the integers $\mathbb Z$ under addition. While I followed most of the proof, it was very long and technical (the video was over one hour), and though the end result was interesting, the proof itself was not particularly motivating to me.
Are there some simpler examples of non-trivial fundamental groups of (path-connected) topological spaces, to help motivate the definition of fundamental group and also to see how one might go about computing the fundamental group of a space?
There does not exist any simpler example. Indeed, proving that any space has nontrivial fundamental group is at least as hard as proving that $S^1$ has nontrivial fundamental group, because if any space has nontrivial fundamental group it follows immediately that $S^1$ must have nontrivial fundamental group. To see this, suppose $\pi_1(S^1,x_0)$ is trivial. Then in particular the identity map of pointed spaces $(S^1,x_0)\to (S^1,x_0)$ is nullhomotopic. This then gives a nullhomotopy of any pointed map $(S^1,x_0)\to (Y,y_0)$ for any pointed space $(Y,y_0)$, by simply composing with a nullhomotopy of the identity map on $(S^1,x_0)$, and so $\pi_1(Y,y_0)$ is trivial.