Let $k$ be a field and let $B$ be a $k$-algebra, then $M_n(k)\otimes_kB\cong M_n(B)$.
There is no need to read the following texts.
A brief overview of what I know, and what I did:
Let $E_{ij}$ be the matrice with 1 in the entry $ij^{\rm th}$, and $0$ elsewhere. Then $E_{ij}$'s form a basis for $M_n(k)$. $M_n(k)\otimes_kB$ is a free $B$-module, with the generating set $\{E_{ij}\otimes1_B\}$. Also we have these relations: $(E_{ij}\otimes1_B)(E_{kl}\otimes1_B)=\delta_k^j(E_{il}\otimes1_B)$. I can not go further, and even I can not recognize if I am walking in a suitable direction or not.
I solved some exercises on tensor products, most of them are solved with the same idea for this problem: Let $G$ be an abelian group, such that the order of any element is finite. Then $G\otimes_{\mathbb{Z}}\mathbb{Q}\cong0$. But that problem has a different nature, and I stuck in that problem, and I don't know how should I show that.
Final Edit: (My solution to $M_n(A)\otimes_kB\cong M_n(A\otimes B)$, where $k$ is a field, and $A$ and $B$ is a $k$-algebras.) (I am not sure if my solution is true or not)
$M_n(A)\otimes_kB$ is a free $B$-module, with the basis $\{(E_{ij}\otimes1_B) \mid 1 \leq i, j \leq n \}$. Now define the map $\varphi$ on the elements of basis as follows:
\begin{gather*} \varphi:M_n(A) \otimes_k B \longrightarrow M_n(A\otimes B)\\ (E_{ij}\otimes1_B) \mapsto E_{ij} \end{gather*}
Then we have
$$\varphi((E_{ij}\otimes1_B)(E_{kl}\otimes1_B))=\varphi(E_{ij}E_{kl}\otimes 1_B)=\varphi(\delta_k^jE_{il}\otimes 1_B)=\delta_k^jE_{il}=E_{ij}E_{kl}=\varphi(E_{ij}\otimes1_B)\varphi(E_{kl}\otimes1_B)$$
As $k$-modules, $M_n(k)$ is isomorphic to $k^{(n^2)}$, and similarly, $M_n(B) \sim B^{(n^2)}$. Therefore, since tensor product distributes over direct sum, $M_n(k) \otimes_k B \sim M_n(B)$ as $k$-modules. The isomorphism is given via $(x_1, ... x_{n^2}) \otimes b \rightarrow (b x_1 , ... b x_{n^2})$. Call this function $\phi$.
The only thing we need to do now is to show that this preserves multiplication. By the distributive property, it suffices to show that it preserves multiplication on pure tensors.
Let $A, B \in M_n(k), x, y \in B$. Then, $\phi(A \otimes x * B \otimes y) = \phi(AB \otimes xy) = xy AB$, and $\phi(A \otimes x) * \phi(B \otimes y) = xA * yB = xy AB$.
Therefore, it preserves multiplication and is an isomorphism.