Why should I study point-set topology?
What initially interested me in topology was the pop-sci rubber sheet stuff or coffee cup-donut stuff or proving fundamental theorem of algebra using curves but now here I'm stuck between distinguishing between $T2.5$ and $T2.500001$ spaces with loads of weird counterexamples and all that.
Also, I don't find any applications of point-set topology mentioned in Munkre's book either except for maybe finding weird counterexamples in real analysis but then honestly I find that to be very boring too (maybe something is wrong with my mathematical interests).
Those weird counterexamples are, from a certain standpoint, the reason to love point-set topology: they provide you with a much better understanding of how things you think you understand can go wrong. What point-set topology really does is explain structure and lets you evaluate new objects (and sometimes old ones) to see where their structure is familiar and where it's odd, and that can help lead you in new directions.
But let's take an example: the Baire Category Theorem is an abstract result that says that if sets are nowhere dense (i.e. the interior of their closure is empty) then a countable union of them has the same property. A Baire-zero function is just a continuous function, and a Baire-one function is the pointwise limit of continuous functions.
To be less abstract: let $f_n : [0,1] \rightarrow [0,1]$ be defined by $$f_n(x)=\left\{ \begin{eqnarray} 0 & \mbox{if} & x \in \{0,1\} \\ 1 & \mbox{ if } & \frac{1}{n} < x <1-\frac{1}{n} \\ nx & \mbox{ if } & 0 < x < \frac{1}{n} \\ n(1-x) & \mbox{ if } & 1-\frac{1}{n}<x<1 \end{eqnarray} \right. $$ so the $f_n$ are trapezoids. Their limiting function is Baire-one by definition (since they're all continuous) and is $f:=\chi_{[0,1]}-\chi_{\{0,1\}}$ where $\chi_A$ is the characteristic function of a set $A$ -- and is clearly discontinuous. (We can, as you've probably guessed, extend this to find Baire-two functions that are the pointwise limits of Baire-one functions, etc. And... there are functions that do not belong to any finite Baire-class!)
Those kind of functions will be familiar to you already as a source of counterexamples (for things like uniform convergence of Lebesgue integrals, for example). Now, we can use the Baire category theorem to show that Baire-one functions have a point of continuity in every closed interval that it's defined on, which tells us something interesting: the limit of pointwise continuous functions can't be too discontinuous. (That said, those discontinuities can form quite a large set in measure-theoretical terms; see https://math.stackexchange.com/a/112133/13130 ).
We know another kind of thing that can't have too many discontinuities: derivatives of differentiable functions. And indeed, we can show (relatively easily) that derivatives must be Baire-one functions. Now, I wrote $f$ deliberately as a difference of characteristic functions, because, going all the way back to point-sets, the characteristic functions of $F_\sigma$ sets (countable unions of closed sets) are exactly the Baire-one functions. Better still, the discontinuity set of a derivative must be a first-category $F_\sigma$-set. So we get a (probably surprising) result: you can know a lot about derivatives by looking at the countable unions of closed sets!
[Thanks to Dave L. Renfro for the link above, and for taking the time to correct my careless original post!]