Let's put it formally...
Let $n$ be a positive integer and $E = \{-1,+1\}^n$. Consider the set $\mathcal{P}$ of all the probability measures $\mu$ on $E$ such that $$ \mu ( \pi_i^{-1} \{-1\} ) = \mu ( \pi_i^{-1} \{+1\} ) = \frac12 $$ where $\pi_i : E \rightarrow \{-1,+1\}$ is the canonical projection onto the $i^\text{th}$ component of $E$, i.e. $\pi_i(x_1, \dots, x_n) = x_i$.
How can I parametrize $\mathcal{P}$?
Also, letting $\mathcal{C}$ be the set of all $n \times n$ correlation matrices, consider the map $c: \mathcal{P} \rightarrow \mathcal{C} $ that assigns to each probability measure in $\mathcal{P}$ its correlation matrix. Is $c$ injective? Surjective?
For the simple case $n=2$, it is clear to me that we can put $\mathcal{P}$ in a bijection with $[0,\frac12]$. For $a \in [0,\frac12]$, define $\mu$ as $$ \mu \{-1,-1\} = \mu \{+1,+1\} = a \\ \mu \{-1,+1\} = \mu \{+1,-1\} = \frac12 - a $$ It's also clear that $c$ is bijective since the correlation is $4a-1$.
But what about the case of arbitrary $n$?
The measures you are interested in are called symmetric Bernoulli distributions. The question which correlations are possible for such distributions is answered in the paper Admissible Bernoulli correlations.
To quote from the paper:
They further characterize (in their Theorem 2) all possible correlations of symmetric Bernoulli distributions in terms of the $\text{CUT}_n$ polytope.