Let $\Omega \subseteq \Bbb R^n$, we define the outer measure the following way : $m^*(\Omega):= \inf\{ \sum_{j \in J} \text{vol } B_j \lvert \{B_j\} \text{ is countable covering by boxes of } \Omega \}$ where a box $B$ is $B:=\Pi_{i=1}^n (a_i,b_i)$ and vol($B)=\Pi_{i=1}^n (b_i-a_i)$.
It is said in my lectures notes that this outer measure does not satisfy countable additivity : if $A,B$ disjoint then $m^*(A \cup B) = m^*(A) + m^*(B)$.
Can you give me a counterexample for this i.e. $A,B$ disjoint sets such that $m^*(A \cup B) \neq m^*(A) + m^*(B)$.
$\newcommand{\a}{\mathcal{A}}\newcommand{\p}{\mathcal{P}}\newcommand{\i}{\mathcal{I}}$I will demonstrate a favourite proof of mine.
Note that $\sqcup$ denotes disjoint union. Since $m^\ast$ satisfies $(2),(3)$ and you want to show it does not satisfy $(1)$, you can let $\mu=m^\ast$ to get the same result. More generally, condition $(3)$ can be relaxed to say: there is at least one open set $G\in\p(\Bbb R)$ with $0\lt\mu(G)\lt\infty$.
Proof:
Again, everywhere you could have replaced $\mu$ with $m^\ast$ and shown that $m^\ast$ cannot satisfy countable additivity - condition $(1)$ - on the pathological family $\{\a_k:k\in\Bbb N\}$.
For Lebesgue's measure, pathological sets like $\a$, which "change" in (outer) measure as you move them, are deemed non-measurable; we restrict the sigma algebra to a certain collection of nice sets - $\a$ is definitely not in that collection. This is just one of many examples.