I believe that (i.e., it would be convenient if, and visually appears that) the product of the two complementary error functions:
$$\operatorname{erfc}\left[\frac{a-x}{b}\right]\operatorname{erfc}\left[\frac{a+x}{b}\right]$$
will have a solution, or can be approximated with a solution, of a Gaussian form (i.e., $c\operatorname{exp}\left[-\frac{x^2}{2d^2}\right]$, where $c$ and $d$ are functions of $a$ and $b$) when $a>0$ and $c>0$, however I cannot find a proof of this. Any help?

Let $x = a$. Then, the product becomes $\mathrm{erfc}(2a/b)$. If the product were equal to an exponential function, that would mean we could express $\mathrm{erfc}$ in terms of elementary functions, which, as far as I know, is impossible.