Proof by contradiction using counterexample

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Why can't we use one counterexample as the contradiction to the contradicting statement?

Example: Let a statement be A where a-->b. We can prove A is not true by finding a counter example.

Now, in another space and time, Let a new statement be B where it is the same as a-->not b.

Why can't we prove B is not true by finding a counter example? Thus, a contradiction and A is true?

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Instead of having both $A$, $B$, $a$ and $b$, let's make some of them $p$ and $q$.

Also, since you're talking about counterexamples, there must be a quantifier somewhere, so I guess you actually mean something like

$$ A \equiv \forall x\,(p(x)\to q(x)) $$ $$ B \equiv \forall x\,(p(x)\to \neg q(x)) $$

Having a counterexample to $A$ means that we have a particular $x_0$ such that $p(x_0)$ is true but $q(x_0)$ is false.

Similarly, having a counterexample to $B$ means that we have an $x_1$ such that $p(x_1)$ is true and $q(x_1)$ is also true.

There's no contradiction in having both counterexamples at the same time, because $x_0$ and $x_1$ will in general be different things -- as evidenced by the fact that $q$ is false for one of them and true for the other.

And also,just knowing these two counterexamples doesn't tell us anything about whether $p(x)$ is true for any other $x$, different from $x_0$ and $x_1$. There may be lots of other $x$s that $p$ is false for. Or there might not -- the example doesn't tell us anything either way.

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You can disprove the statement $a \implies \sim b$ using a counterexample if you can find one. However, this does not prove the statement $a \implies b$. This is because the negation of $a \implies \sim b$ isn't $a \implies b$.

Recall that the negation of an implication is not an implication. $\sim (a \implies b) \equiv a \wedge \sim b$. In words, this says that the negation of "a implies b" is equivalent to "a and not b".

You are right that if a statement $B$ is the negation of a statement $A$, then $A$ being false implies $B$ is true, and $B$ being false implies $A$ is true. The problem is, the negation of an implication is not an implication.

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Remember that: $(a\implies b) \equiv (\neg a \lor b)$

Hence: $\therefore \neg (a\implies b) \equiv (a \land \neg b)$

The counter example of the implication is an event where $a$ happens and not $b$.

${\begin{array}{|c|c|c|c|}\hline a & b & a\to b & a \land \neg b \\ \hline\hline F & F & T & F \\\hline F & T & T & F \\ \hline T & F & F & \color{red}{T} \\\hline T & T & T & F \\ \hline \end{array}}$