In an isosceles right angled triangle, vertex opposite to the hypotenuse which has $90^\circ$ is always on the perpendicular bisector of the hypotenuse.
So my question is, if we consider a sides of length $a$ and hypotenuse as $c$, then how to prove that length of segment $c$ is not a rational multiple of length of segment $a$.
Sum of lengths of two sides of a traingle is always greater than third side. So we have $2a>c$ so $c/a<2$ and $a<c$ so $1<c/a$, or $1<c/a<2$. But I unable to go any further.



Ancient Greeks were well aware that certain length ratios they could easily construct had to be irrational. One such ratio was, indeed, the hypotenuse/side ratio in an isosceles right triangle.
This ratio can be proved irrational by contradicting the existence of a fraction in lowest terms. For suppose such a fraction $p/q$ were to exist. Then by adjoining the original triangle with a congruent one sharing a leg, forming a similar larger right triangle, the same ratio would be rendered as $2q/p$. Therefore $p/q=2q/p$, and both are then equal to $(2q-p)/(p-q)$.
But $p>q$ since $p$ is the hypotenuse of the right triangle and $q$ is a leg, and $p<2q$ from the hypotenuse being shorter than the path between its endpoints via the legs. So the denominator $p-q$ is positive and less than $p$, while the numerator $2q-p$ is also a whole number, contradicting the requirement that $p/q$ was to be in lowest terms.
Similar arguments could be applied to what we now call the golden ratio (which can be constructed from a right triangle whose legs are in the ratio $2:1$) and the ratio of the legs in the right triangle obtained by dividing an equiliateral triangle along its mirror plane. That such quantities could be rendered beyond our ability to measure them exactly is a remarkable feature of elementary geometry.