Pythagoras Theorem is a theorem about right-angle triangles so if we know one of the angles (except $90^{\circ}$, which is not the case in here), then we know all of the angles and knowing one of the sides of the triangle is enough for finding other two.
$$a = b\tan\theta$$
Where $\theta$ is the angle opposite to $a$
From this:
$$b = \frac{a}{\tan\theta}$$