I have a distribution who's moment generating function is the product of two exponentially distributed variables moment generating functions. If I wanted to generate samples from the distribution, would it be appropriate to generate a random sample from the exponential distribution and multiply it by two? For clarification the PDF is below:
$$f(x) = \lambda^2 x\cdot exp(-\lambda x), x \geq 0 $$
The MGF calculated for this PDF was:
$$M(t) = \lambda^2/(\lambda - t)^2$$

The exponential distribution has the scaling property. If $X \sim exp(\lambda)$, then $k \cdot X \sim exp(\lambda/k)$ for any $k > 0$, in particular $k = 2$, and the pdf of $exp(\lambda/2)$ is not equal to the expression you are giving, so the answer to your question is no.