Let $(X,d)$ be a metric space and $\mu$ a Borel probability measure.
Suppose that for every $\epsilon>0$ we have that $\mu(B_{\epsilon }(x))=c_{\epsilon}>0$ a.e.
Is this enough to show that for every $\epsilon$ there exist a countable set $K\subset X,$ such that $\mu(\cup_{x\in K}B_{\epsilon}(x))=1?$
Your assumption implies that your metric space is separable.
Exercise: Suppose a metric space is not separable. Then for some $\epsilon > 0$, one can find an uncountable family of pairwise disjoint open balls each of radius $\epsilon$.
So you can take $K$ to be a countable dense subset of $X$.