Given a set $U=\{1,2,...,n\}$, and its power set $\mathcal S=\{S_1,...,S_{2^n-1}\}$(without emptyset $\emptyset$), a minimum coverable combination is $S_i\cup...\cup S_k=U$ and $S_i,...,S_k$ are pairwise disjoint.
For example, when $U=\{1,2,3\}$, then $\mathcal S=\{\{1\},\{2\},\{3\},\{1,2\},\{1,3\},\{2,3\},\{1,2,3\}\}$ and a minimum coverable combination is $S_4=\{1,2\}$ and $S_3=\{3\}$ then $S_4\cup S_3=U$ and $S_4\cap S_3=\emptyset$.(don't count the permutations so $S_4\cup S_3$ is considered the same as $S_3\cup S_4$)
Now the question is to prove the number of minimum coverable combination of $U$ is less than or equal to $2^n$
Let $U = \{ 1, 2, 3, 4, 5 \}$. Here are some minimum coverable combinations of $U$:
$\begin{align*} 1. \: & \{ 1, 2, 3, 4, 5 \} \\ 2. \: & \{ 1 \}, \{ 2, 3, 4, 5 \} \\ 3. \: & \{ 2 \}, \{ 1, 3, 4, 5 \} \\ 4. \: & \{ 3 \}, \{ 1, 2, 4, 5 \} \\ 5. \: & \{ 4 \}, \{ 1, 2, 3, 5 \} \\ 6. \: & \{ 5 \}, \{ 1, 2, 3, 4 \} \\ 7. \: & \{ 1, 2 \}, \{ 3, 4, 5 \} \\ 8. \: & \{ 1, 3 \}, \{ 2, 4, 5 \} \\ 9. \: & \{ 1, 4 \}, \{ 2, 3, 5 \} \\ 10. \: & \{ 1, 5 \}, \{ 2, 3, 4 \} \\ 11. \: & \{ 2, 3 \}, \{ 1, 4, 5 \} \\ 12. \: & \{ 2, 4 \}, \{ 1, 3, 5 \} \\ 13. \: & \{ 2, 5 \}, \{ 1, 3, 4 \} \\ 14. \: & \{ 3, 4 \}, \{ 1, 2, 5 \} \\ 15. \: & \{ 3, 5 \}, \{ 1, 2, 4 \} \\ 16. \: & \{ 4, 5 \}, \{ 1, 2, 3 \} \\ 17. \: & \{ 1 \}, \{ 2 \}, \{ 3, 4, 5 \} \\ 18. \: & \{ 1 \}, \{ 3 \}, \{ 2, 4, 5 \} \\ 19. \: & \{ 1 \}, \{ 4 \}, \{ 2, 3, 5 \} \\ 20. \: & \{ 1 \}, \{ 5 \}, \{ 2, 3, 4 \} \\ 21. \: & \{ 2 \}, \{ 3 \}, \{ 1, 4, 5 \} \\ 22. \: & \{ 2 \}, \{ 4 \}, \{ 1, 3, 5 \} \\ 23. \: & \{ 2 \}, \{ 5 \}, \{ 1, 3, 4 \} \\ 24. \: & \{ 3 \}, \{ 4 \}, \{ 1, 2, 5 \} \\ 25. \: & \{ 3 \}, \{ 5 \}, \{ 1, 2, 4 \} \\ 26. \: & \{ 4 \}, \{ 5 \}, \{ 1, 2, 3 \} \\ 27. \: & \{ 1 \}, \{ 2, 3 \}, \{ 4, 5 \} \\ 28. \: & \{ 1 \}, \{ 2, 4 \}, \{ 3, 5 \} \\ 29. \: & \{ 1 \}, \{ 2, 5 \}, \{ 3, 4 \} \\ 30. \: & \{ 2 \}, \{ 1, 3 \}, \{ 4, 5 \} \\ 31. \: & \{ 2 \}, \{ 1, 4 \}, \{ 3, 5 \} \\ 32. \: & \{ 2 \}, \{ 1, 5 \}, \{ 3, 4 \} \\ 33. \: & \{ 3 \}, \{ 1, 2 \}, \{ 4, 5 \} \\ 34. \: & \{ 3 \}, \{ 1, 4 \}, \{ 2, 5 \} \\ 35. \: & \{ 3 \}, \{ 1, 5 \}, \{ 2, 4 \} \\ 36. \: & \{ 4 \}, \{ 1, 2 \}, \{ 3, 5 \} \\ 37. \: & \{ 4 \}, \{ 1, 3 \}, \{ 2, 5 \} \\ 38. \: & \{ 4 \}, \{ 1, 5 \}, \{ 2, 3 \} \\ 39. \: & \{ 5 \}, \{ 1, 2 \}, \{ 3, 4 \} \\ 40. \: & \{ 5 \}, \{ 1, 3 \}, \{ 2, 4 \} \\ 41. \: & \{ 5 \}, \{ 1, 4 \}, \{ 2, 3 \} \\ \end{align*}$
There are more than $2^5 = 32$, so the claim is false.