SECTION 2.4 A Deductive Calculus In Enderton's A Mathematical Introduction to Logic divides the set of axioms into several groups. The first group is called "tautologies" on p114, which are obtained from tautologies in Sentential Logic, by treating the primary formulas in FOL as sentence symbols in SL.
Theorem 24B on p115 says logical implication in FOL and tautological implication in SL are equivalent. Is $\vdash$ in Theorem 24B intended to mean logical implication in FOL? Should $\vdash$ be $\models$ instead? (Given that this is from a section for a proof system, and soundness and completeness haven't been introduced, it is possible that $\vdash$ is not a typo.)

As spaceisdarkgreen says, there is no typo here: Enderton means "$\vdash$" in the theorem, and "logical entailment" ($\models$) in the remark. The remark observes that there is a gap between $\models$ and tautological implication. The theorem on the other hand says that we can "reduce" $\vdash$ to tautological implication: if we want to know whether $\Gamma\vdash\varphi$, it's enough to know whether $\Gamma\cup\Lambda$ tautologically implies $\varphi$.
Despite this, the remark and theorem are connected, even if somewhat loosely. The point is that that theorem should be thought of as partially filling in the gap exhibited in the remark by showing how tautological entailment can be connected to a particular relation on first-order sentences which we know is going to wind up being the same as $\models$ (see the introduction to Section $2.4$). So while we'll have to wait for the soundness/completeness theorem to be able to prove the equivalence we really want, namely that $\Gamma\models\varphi$ iff $\Gamma\cup\Lambda$ tautologically implies $\varphi$, the theorem following the remark is still relevant.
It's true that if we forget about the context in which we've introduced $\vdash$, the connection becomes much more tenuous (although it's still there: both the remark and theorem focus on the extent to which propositional logic can be applied to first-order logic in some sense). However, that context is there for a reason: all of this is much harder to motivate if we don't begin with the explicit goal of giving a "concrete" description of $\models$.