A pair $(X, Y)$ is a point on a single circle $\{(x, y) \mid x^2 + y^2 \le 1\}$. Place this point in the form It is determined randomly and uniformly distributed.
What I want to show is $X$ and $Y$ are not independent But $\operatorname{Cov}[X, Y] = 0.$

Maybe you would like to consider the approach that doesn't require explicitly writing down the densities (formally it can be done with indicator function and Dirac Delta and is not really very advanced).
The calculation-free approach below is applicable for both uniform over the circle or over the disk.
To show $Cov[X,Y] = E[XY] - E[X]E[Y]\overset{?}{=}0$, it suffices to notice that
$E[X] = 0$ due to mirror (refection) symmetry with respect to the $y$-axis. Similarly, $E[Y] = 0$ due to symmetry about the $x$-axis.
$E[XY] = 0$ for the following reasons. The product $xy$ has a magnitude that is four-fold symmetric in the four quadrants, while the sign of $xy$ in the four quadrants are alternating: positive in 1st, negative in 2nd, positive in 3rd, and negative in 4th. Whatever the joint density $f_{XY}(x,y)$ looks like, it is also four-fold symmetric and the integral $\int xy\cdot f_{XY}(x,y) dxdy$ is going to have the four parts that cancel exactly.
Thus $Cov[X,Y] = E[XY] - E[X]E[Y] = 0 - 0 = 0$
The fact that $X$ and $Y$ are dependent is simply because that the range (a.k.a the domain, or the support) of $X$ is a function of $Y$ and vice versa. When the the range depends on the other one, there's your dependency.
As long as by definition your 2-dim distribution is zero "outside" where $x^2+y^2>1$, the two random variables (the two coordinates) are dependent. This has nothing to do with uniformity or symmetry.