Suppose I have a finite set $\mathcal{P} := \{x_1, x_2, \ldots , x_n\} \subset \mathbb{R}^d$.
Is there any way to characterize the couples $(x_i, x_j)$ such that there exists a ball $B$ with $x_i, x_j \in B$ but all the other points in $\mathcal{P}$ are not inside $B$.
Some obvious remarks on the question :
$\bullet$ For any point $x_i$, take the point $x_j$ that is closest to $x_i$, then $(x_i, x_j)$ verifies the desired property.
$\bullet$ For a couple $(x_i, x_j)$, if there exists an $x_k$ on the segment joining the two points, then $(x_i, x_j)$ cannot verify the property.
$\bullet$ It also seems that the edges between "adjacent extremal points of the convex hull'' (I don't know how to call these) always satisfy the property, as we may take a sphere with a centre far away.
This shows that this property is not really trivial. I have made a small approximate figure in the plane here, with the green edges representing the edges satisfying my problem (I only have an online drawing tool available :) ):

I am really looking for any necessary and/or sufficient condition, or reference if this has a name. Of course a partial answer on the plane would be nice already.
My further objective is to get a necessary and sufficient condition for the same property but for more than two points, and to impose that the center of the sphere lies outside the convex hull of the points.
Assuming closed balls are allowed, $(x_i, x_j)$ have the property if there is $x$ such that $x_i$ and $x_j$ are the two closest points to $x$ in your set, i.e. $\max(|x-x_i|, |x-x_j|) < |x-x_k|$ for all $k \notin \{i,j\}$. Note that if $x$ works here, so does any point in some neighbourhood of $x$. Thus for simplicity we can restrict our attention to the points whose distances to all the $x_j$ are distinct, i.e. the complement $U$ of the union of hyperplanes $P_{ij} = \{x: |x - x_i|=|x-x_j|\}$, $1 \le i < j \le n$. These hyperplanes divide $U$ into domains, in each of which the points $x_i$, $x_j$ are placed in a fixed order by their distances to a point in the domain. $(x_i, x_j)$ have the property if at least one of these domains has $x_i$ and $x_j$ as the first two in that order.